Rotational spectroscopy @ISMO

High resolution spectroscopy from the millimeter-wave to the terahertz domain.

Rotational spectroscopy [@ISMO](http://www.ismo.universite-paris-saclay.fr/)

Recent Publications

October 2022 J. Phys. Chem. A
Pure rotational spectroscopy of the CH$_2$CN radical extended to the sub-millimeter wave spectral region
Pure rotational spectroscopy of the CH$_2$CN radical extended to the sub-millimeter wave spectral region

We present a thorough pure rotational investigation of the CH2CN radical in its ground vibrational state.

Cite ESI Project Project Project DOI
October 2022 J. Am. Chem. Soc.
Ring-opening dynamics of the cyclopropyl radical and cation: the transition state nature of the cyclopropyl cation
Ring-opening dynamics of the cyclopropyl radical and cation: the transition state nature of the cyclopropyl cation

We provide compelling experimental and theoretical evidence for the transition state nature of the cyclopropyl cation.

Cite HAL DOI
July 2022 The Journal of Chemical Physics
Tunneling motion and splitting in the CH$_2$OH radical: (Sub-)millimeter wave spectrum analysis
Tunneling motion and splitting in the CH$_2$OH radical: (Sub-)millimeter wave spectrum analysis

We report on the theoretical and experimental investigation of the CH2OH radical pure rotational spectrum in the (sub-)millimeter wave domain.

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