Rotational spectroscopy @ISMO

High resolution spectroscopy from the millimeter-wave to the terahertz domain.

Rotational spectroscopy [@ISMO](http://www.ismo.universite-paris-saclay.fr/)

Recent Publications

January 2023 Journal of Molecular Spectroscopy
The bending of C$_3$: Experimentally probing the $l$-type doubling and resonance
The bending of C$_3$: Experimentally probing the $l$-type doubling and resonance

We report a joint rovibronic and rovibrational study of C3.

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October 2022 J. Phys. Chem. A
Pure rotational spectroscopy of the CH$_2$CN radical extended to the sub-millimeter wave spectral region
Pure rotational spectroscopy of the CH$_2$CN radical extended to the sub-millimeter wave spectral region

We present a thorough pure rotational investigation of the CH2CN radical in its ground vibrational state.

Cite ESI Project Project Project DOI
October 2022 J. Am. Chem. Soc.
Ring-opening dynamics of the cyclopropyl radical and cation: the transition state nature of the cyclopropyl cation
Ring-opening dynamics of the cyclopropyl radical and cation: the transition state nature of the cyclopropyl cation

We provide compelling experimental and theoretical evidence for the transition state nature of the cyclopropyl cation.

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